X-ray spectroscopy is a powerful tool demanded across multiple communities as it allows for tracing of structural dynamics [1], detection of electronic structure changes in chemical compounds [2], heritage studies [3] etc. This demand in the user community has led to a development of an X-ray spectroscopy station at ELI Beamlines.
ELI Beamlines is a part of the European Extreme Light Infrastructure Consortium, the world’s largest infrastructure focused on the development and use of high power lasers. Its X-ray spectroscopy station utilizes a laser-driven Cu-tape and water-jet plasma X-ray sources (PXS) with the ultimate goal to perform pump-probe experiments with the inherent pulse synchronization, due to the use of the same laser for the system excitation and feeding the PXS source. In-house built L1 Allegra is the laser of choice [4], with 15 fs pulse energy and 1 kHz repetition rate. The station is built in a von Hamos geometry and automated to a large degree.
As the pump-probe experiments are planned to be conducted at a high repetition rate, a specific care is taken of the development of sample delivery system with an appropriate sample circulation so that every new pulse meets a fresh sample portion.
Thus, in the talk I will focus on the state-of-the-art of the X-ray spectroscopy in general and at ELI Beamlines in particular, describe our status and progress in sample systems, notably including liquid samples as well as talk about the X-ray sources used for the X-ray spectroscopy.
References:
[1] M. Naumova et al., Structural dynamics upon photoexcitation-induced charge transfer in a dicopper(i)-disulfide complex. Phys.Chem.Chem.Phys., 2018, 20,6274
[2] A. Zymaková et al., X-ray spectroscopy station for sample characterization at ELI Beamlines. Sci. Rep., 2023, 13, 17258
[3] A. Zymaková et al., A fast-integrated x-ray emission spectrometer dedicated to the investigation of Pt presence in gold Celtic coins 3rd-1st century BCE). X-ray spectrometry, 2023, 52(6), 401-411
[4] A. Zymaková et al., First experiments with a water-jet plasma X-ray source driven by the novel high-power-high-repetition rateL1 Allegra laser at ELI Beamlines. J. Synchrotron Rad., 2021, 28, 1778-1785